有机化学第二版徐寿昌主编 第2章 烷烃第15章 硝基化合物和胺

1.CH3CH2CNH3O+CH3CH2COOHCH3CH2CON(CH2CH2CH3)CH3ISOCl2LiAlH4CH3CH3CH2COCl(CH3CH2CH2)3NCH3(CH3CH2CH2)2NH2.CH3NH1,CH3I1,22,Ag2O,H2OCH3+NCH3CH3+--OHNCH3CH3CH2=CHC=CH2O+CH32,Ag2O,H2ONOCH3CH3CH3OH(CH3)3N3,CNKCOBrCH(COOC2H5)2CNCOCH(COOC2H5)21,NaOC2H52,C6H5CH2ClOCOOC2H5-1,H2O,OH+2,HCCOCOOH+COOHH2NCCH2C6H5COOHNCCH2C6H5COOC2H5COOHHOOCCHCH2C6H5NH2

七、完成下列转化：

1.

CH3CHCH2CH2OHCH3CH3CHCH2CH2OHCH3NH3[O]CH3CHCH2NH2CH3CH3CHCH2COOHCH3Br2,NaOHSOCl2CH3CHCH2COClCH3CH3CHCH2NH2CH3

CH3CHCH2CONH2CH3

2.CH3CHCH2CH2OHCH3CH3CHCH2CH2OHCH3CH3CHCH2CH2NH2CH3SOCl2CH3CHCH2CH2ClCH3CH3CHCH2CH2CH2NH2CH3SOCl2NaCNCH3CHCH2CH2ClCH3CH3CHCH2CH2CNCH3NH3CH3CHCH2CH2NH2CH33.CH3CHCH2CH2OHCH3CH3CHCH2CH2OHCH3H2,CatCH3CHCH2CH2CH2NH2CH3H2NCH2CH2CH2CH2NH24.CH2=CH2Br2CH2=CH25.BrCH2CH2BrCH3CH2CN2NaCNNCCH2CH2CNH2,CatH2NCH2CH2CH2CH2NH2CH2=CH2CH2=CH2HBrCH3CH2BrNaCNCH3CH2CN6.CH3CH=CH2CH3CH=CH2Br2CH3CHCOOHCH2COOHCH3CHCH2BrBr2NaCNCH3CHCH2CNCNH2O,H+CH3CHCOOHCH2COOH

7.CH3NH2NO2CH3[O]COOHNO2COClSOCl2NH3NO2CONH2Br2NaOHNH2NO2NO2NO2NO2

八、以苯，甲苯以及三个碳原子以下的有机化合物为原料，合成下列化合物:

1.COOHCH3HNO3H2SO4CH3[O]COOHFe/HClCOOH2.NH2NH22HNO3NO2NO2Na2SNO2NO2H2SO4NO2NH2NH2NO2NH23.NH2NH2Fe/HClH2SO4NO2HNO3H2SO4NHCOCH3HNO3H2SO4SO3HNO2HCl,H2ONH2CH3COClNHCOCH3NH2SO3HNO2Fe/HClNH2NH2SO3H

NH24.3HNO3NO2NH4HSO2NNO2CH3O2NNH2O2NCH35.NO2CH3SO2NHH2SO4NO2CH3NO2NH2HNO3H2SO4NO2SO2NHNO22HSO3ClSO2ClNO2Fe/HClNH2NO26.

NHNH2NO2Zn,NaOH/C2H5OHNHNH7.CH3NHCH2ClCH2CH3NH2Cl2,hvCH3

CH3CH2ClNHCH2