新型吡咯烷类有机分子催化剂的合成及其在不对称Mannich反应中的应用【文献综述】

[12] Vignola N, List B. Catalytic asymmetric intramolecularα-alkylation of aidehydes [J].J, Am.

Chem. Soc., 2004, 126: 450-451.

[13] Hoang L, Bahnmanyer S, Houk K N, List B. Kinetic and Stereochemical Evidence for the

Involvement of Only One Proline Molecule in the Transition States of Proline-Catalyzed Intra- and Intermolecular Aldol Reactions [J]. J. Am.Chem. Soc., 2003, 125: 16-17. [14] Zhuo T, Fan J，L Z Gong. Novel Small Organic Molecules for a Highly Enantioselective

Direct Aldol Reaction [J]. J. Am. Chem. Soc., 2003, 125 (18): 5262-5263.

[15] Saito S, Yamamoto H. Design of acid-base catalysis for the asymmetric direct aldol reaction

[J]. Acc. Chem. Res., 2004, 37: 570-579.

[16] Tang Z, Yang Z H, Cun L F, et a1. Small peptides catalyze highly enantioselective direct

aldol reactions of aldehydes with hydroxyacetone: unprecedented regiocontrol in aqueous media [J]. Org. Lett., 2004, 6: 2285-2287. Krarttiger P, Kovasyr, Revell J D, et a1．Increased [17] structural complexity leads to higher activity: peptides as efficient and versatile catalysts for

asymmetric aldol reaction [J]. 0rg. Lett., 2005, 7: 1101-1103.

[18] Ibrahem I, Zou W B, Casas J, et a1. Direct organocatalytic enantioselective α

-aminomethylation of ketones [J]. Tetrahedron., 2006, 62(2/3) 357-364.

[19] Notz W, Tanaka F, Watanabe S, et a1. The Direct Organocatalytic Asymmetric Mannich

Reaction: Unmodified Aldehydes as Nucleophiles [J]. J. Org. Chem., 2003, 68(25): 9624-9634.

[20] Hayashi Y, Tsuboi W. Ashimine I, et a1. The Direct and Enantioselective, One-Pot,

Three-Component, Cross-Mannich Reaction of Aldehydes [J]. Angew. Chem. Int. Ed., 2003, 42(31): 3677-3680.

[21] Cordova A. One-Pot Organocatalytic Direct Asymmetric Synthesis of γ-Amino Alcohol

Derivatives [J]. Synlett., 2003, 11: 1651-1654.

[22] Cobb A J A, Shaw D M, Longbottom D A, et a1. Organocatalysis with proline derivatives:

improved catalysts for the asymmetric Mannich, nitro-Michael and aldol reactions [J]. Org. Biomo1. Chem., 2005, 3(1): 84-96.

[23] Cobb A J A, Shaw D M , Ley S V. 5-Pyrrolidin-2-yltetrazole: A New, Catalytic, More Soluble

Alternative to -Proline in an Organocatalytic Asymmetric Mannich-type Reaction [J]. Synlett, 2004, 3: 558-560.

[24] Cordova A, Barbas C F H I. anti-Selective SMP-catalyzed direct asymmetric Mannich-type

reactions: synthesis of functionalized amino acid derivatives [J]. Tetrahedron Lett., 2002, 43(43):7749-7752.

[25] Mitsumori S, Zhang H, Cheong P H Y, et a1. Direct Asymmetric anti-Mannich-Type

Reactions Catalyzed by a Designed Amino Acid [J]. J. Am. Chem. Soc., 2006, 128(4): 1040-1041.

[26] Cheong P H Y, Zhang H, Thayumanavan R, et a1. Pipecolic Acid-Catalyzed Direct

Asymmetric Mannich Reactions [J]. Org. Lett., 2006, 8(5): 811—814.

[27] Akiyama T, hoh J, Fuchibe K. Recent Progress in Chiral Br?nsted Acid Catalysis [J]. Adv.

Synth. Cata1., 2006, 348(9): 999-1010.

[28] Taylor M S, Jacobsen E N. Asymmetric Catalysis by Chiral Hydrogen-Bond Donors [J].

Angew. Chem . Int. Ed., 2006, 45(10): 1520-1543.

[29] Connon S J. Organocatalysis Mediated by (Thio)urea Derivatives [J]. Chem. Eur. J., 2006,

12(21): 5418-5427.

[30] Akiyama T, hoh J, Yokata K, et a1. Enantioselective Mannich-Type Reaction Catalyzed by a

Chiral Br?nsted Acid [J]. Angew. Chem. Int Ed., 2004, 43(12): 1566-1568.

[31] Akiyama T, Saitoh Y，, Morita H, et a1. Enantioselective Mannich-Type Reaction Catalyzed

by a Chiral Br?nsted Acid Derived from Taddol [J]. Adv. Synth. Catal., 2005, 347(11-13):1523-1526.

[32] Honshi Y, Yabuta T, Takemoto Y. Bifunctional thiourea-catalyzed enantioselective double

Michael reaction of γ,δ-unsaturated β-ketoester to nitroalkene: asymmetric synthesis of (?)-epibatidine [J]. Tetrahedron Lett., 2004, 45(50): 9185-9188.