番茄红素的提取工艺研究

【作者单位】广州大学化学化工学院;

【文献出处】 宁波现代食品科技, Modern Food Science and Technology, 编辑部邮箱 2009年 01期

期刊荣誉：ASPT来源刊 CJFD收录刊

【关键词】番茄红素; 浸提; 微波提取; 稳定性

【英文关键词】 Lycopene; extraction; microwave extraction; stability;

【摘要】用番茄作原料,以V(丙酮):V(水)=10:1的丙酮溶液作为提取溶剂,以测定番茄红素紫外扫描光谱为依据,研究了溶剂浸提法、微波提取法提取番茄红素的工艺条件及番茄红素性质。结果表明:微波提取法比溶剂浸提法有较高的提取率,并且节省时间和提取试剂;番茄红素在472nm波长处有最大吸收峰;番茄红素对光、强酸、高温、Fe3+和Cu2+不稳定,对氧化剂、还原剂、弱酸、碱等较稳定。

【英文摘要】The application of solvent extraction and microwave radiation extraction for lycopene extraction from tomatoes was studied and the properties of lycopene were investigated.The results showed that Microwave radiation extraction was more suitable for lycopene extraction due to its higher extraction rate,shorter extraction time and less extraction reagent dosage than solvent extraction.Lycopene had the maximum absorption peak at 472 nm.It was unstable to light,strong acidic,high temperature,Fe3 + and Cu2 +,whi... ：

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【英文篇名】 Experimental Study on Extraction Technology Condition for Lycopene 【作者中文名】 韩国廷;

【作者英文名】 HAN Guo-ting（Vocational Technical College; Liaoning University of Petroleum and Chemical Technology; Fushun; Liaoning 113001）; 【作者单位】 辽宁石油化工大学职业技术学院; 【文献出处】安徽农业科学, Journal of Anhui Agricultural Sciences, 编辑部邮箱 2008年 30期

期刊荣誉：中文核心期刊要目总览 ASPT来源刊 CJFD收录刊 【关键词】番茄红素; 乙酸乙酯; 萃取;

【英文关键词】 Lycopene; Ethyl acetate; Extraction; 【摘要】 [目的]确定番茄红素的提取工艺。[方法]采用正交试验,研究液料比、提取温度、提取时间及提取次数对番茄红素提取率的影响。[结果]乙酸乙酯的浸提效果最好,故选用乙酸乙酯作为浸提溶剂。随着液料比的升高,番茄红素提取率增加,当液料比大于4∶1(ml/g)时,色素提取率增加缓慢。当pH值小于6时,随着pH值的增大,色素提取率增加;当pH值大于6时,随着pH值的增大,色素提取率降低。各因素对番茄红素提取率的影响由大到小依次为:液料比>提取次数>提取时间>提取温度。[结论]番茄红素的最佳提取工艺为:液料比为4∶1(ml/g),提取时间50 min,提取温度45℃,提取次数3次,该条件下,番茄...

【英文摘要】 [Objective] The study was to determine the extraction technology for lycopene.[Method] The orthogonal test was taken to study the effects of liquid-to-solid ratio,extraction temperature,extraction time and extraction times on the extraction rate of lycopene.[Result] The extraction effect with ethyl acetate was the best,so ethyl acetate was selected as the extraction solvent.With the increasing of liquid-to-solid ratio,the extraction rate of lycopene was increased and when liquid-to-solid ratio was above 4∶1...

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（3）中国知识产权网(经查证，该处提供专利说明书)

用检索式A共检出文献16篇，选择3篇如下： 012

【名称】一种从番茄中提取番茄红素的方法 【申请号】03115731.9 【申请人】刘耀北 【发明人】刘耀北

【摘要】本发明属于食品技术领域。本发明公开了一种从番茄中提取番茄红素的工业化生产的皂化方法。本发明的方法优于现有技术的“溶剂法”和“萃取法”，具有工艺简单，生产周期短，设备投资少，效率高的优点，并且无三废排放，不产生二次污染，宜于规模型工业化生产。

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【名称】从番茄皮渣中提取番茄红素的方法 【申请号】200710150585.5 【申请人】 天津科技大学 【发明人】张泽生;赵娟娟;王 浩

【摘要】本发明涉及一种从番茄皮渣中提取番茄红素的方法，其步骤是(1)将番茄皮渣经皮籽分离工序，得到番茄皮和番茄籽；(2)将(1)得到的番茄皮进行粉碎，得到番茄皮浆；(3)对番茄皮浆进行预处理，脱水除杂；(4)把处理后的番茄皮浆加入有机溶剂进行提取，收集提取液，(5)真空浓缩，即制得番茄红素油树脂。本发明提供的提取番茄红素的方法，是利用了番茄加工业废弃物—番茄皮渣作为原料，得到高含量的番茄红素产品。本方法简便易行，原料来源广泛，成本低廉。本发明的实施有利于补充番茄红素生产的原料来源，同时避免了资源浪费和环境污染，又能增加番茄产业的经济效益，开发前景非常广阔。 014

【名称】 一种快速提取番茄红素的方法 【申请号】200710131868.5 【申请人】江南大学 【发明人】张连富;刘泽龙 【摘要】一种快速提取番茄红素的方法，属于食品配料技术领域。本发明从富含番茄红素的原料中提取番茄红素，将富含番茄红素的原料经初步处理后，用超声波/微波协同技术辅助溶剂回流提取番茄红素，浓缩后得番茄红素油树脂产品；并回收溶剂。本发明步骤简单，提取时间大大缩短，避免在提取过程中番茄红素的损失；提取率较高，最高提取率可达到97％；提取过程采用密闭体系，溶剂消耗少，降低了成本，同时提高了生产的安全性；采用微波为加热源，能量直接作用于萃取体系，减少了能量的浪费，具有节能的特点

（4）美国工程索引（EI）

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Title: Study on methods of lycopene extraction (番茄红素的提取方法研究)

Authors: Deng, Yu1 ; Zhang, Wei-Qiang1.

Source: Huagong Xiandai/Modern Chemical Industry

Abstract: Methods of lycopene extraction from tomato were studied. Effects from

extraction temperature, time, feedstock ratio and solvent on extraction result were studied and optimal conditions were determined. Lycopene can be completely extracted

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by using No.6 solvent for the second-level extraction from tomato pulp for a duration of 2-3 hours at ratio of tomato mass to solvent volume of 0.33 g/ml, a pH value of 6 and 35°C and with the addition of assistants. When using microwave radiation, best results can be achieved at a microwave power of 200 W, an extraction time of 80 s and a ratio of tomato mass to solvent volume of 0.5 g/ml. ISSN: 02534320

原文收藏：由资料来源查电子期刊收录及国内馆藏联合目录，得Elsevier Science上有收录。 016

Title: Application of high hydrostatic pressure processing of food to extracting lycopene

from tomato paste waste

（食品加工过程中的高静水压处理方式对从番茄酱中提取番茄红素的应用）

Authors: Jun, X.1

Source: High. Pressure. Res. v 26p 33-41

Abstract: The application of high hydrostatic pressure (HHP) processing of food to extracting lycopene from tomato paste waste was studied. Various experimental conditions of HHP processing process, such as solvents (chloroform, 95% ethanol and distilled water), ethanol concentration (45-95%, v/v). pressure (100-600MPa), duration (1-10min) and solid/liquid ratio (1:1 to 1:8g/ml), were investigated to optimize the extraction process. The experimental results of HHP showed that more lycopene can be extracted from tomato paste waste in only l min at room temperature without any heating process. The highest recovery (92%) was obtained by performing the extractions at 500 MPa pressure, 1 min duration, 75% ethanol concentration, and 1:6 (g/ml) solid/liquid ratio. From the viewpoints of extraction time, the extraction yield and the extraction efficiency, extraction by HHP shows a bright prospect for extracting lycopene from tomato paste waste.

ISSN: 08957959

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Title: Supercritical CO2 extraction of lycopene from tomato industrial waste

（番茄工业废物中番茄红素的超临界二氧化碳萃取法）

Authors: Nobre, Beatriz P.1 ; Pessoa, Fernando L. P.2 ; Palavra, António F.3 ; Mendes,

Rui L.1

Source: CHISA 2006 - 17th International Congress of Chemical and Process Engineering v 93 n 8 Oct 1998 p 255-260 Abstract: Supercritical CO2 extraction of lycopene from tomato industrial waste (mixture

of skins and seeds) was carried out in a flow apparatus at temperatures of 40, 60 and 80°C and pressures of 200 and 300 bar. The effects of the composition of the starting waste, pressure and temperature on the extraction yield were studied. The yield and recovery of trans-lycopene depended on the composition of the starting material: for a batch with lower content in lycopene (128 μg/g, dry basis), there was a quick recovery of the almost all the lycopene (93 %), with a consumption of CO2 of 78 g per g of dry tomato waste, while for the batch with higher content (214 μg/g, dry basis) it was obtained a recovery of 86% of the lycopene using 220 g of CO2 per g of dry tomato waste. These supercritical extractions were carried out at a pressure of 300 bar and a

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temperature of 60°C. When the pressure was lowered to 200 bar the recovery of the trans-lycopene dropped to 30 %. The effect of the extraction temperature is more complex. When the temperature increased from 40 to 60°C the recovery increased, but a further rise of the temperature to 80°C led to a decrease of the trans-lycopene recovery, although the total lycopene (cis plus trans) remained the same of that at 60°C. An empirical model was used to describe the cumulative curves of the supercritical CO2 extraction of the lipids (containing the lycopene) from the tomato waste and a good agreement was reached. ISSN: 8086059456

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Title: A review on lycopene - Extraction, purification, stability and applications

（回顾关于番茄红素——提取，净化）

Authors: Choksi, Pratik M.1 ; Joshi, Vishal Y.2, 3

Source: Choksi, Pratik M.1 ; Joshi, Vishal Y.2, 3 v10 n 2 April/June 2007 p 289-298 Abstract：Lycopene is a functional component of great dietary importance obtained from many plant sources. In this article, we address the extraction of lycopene from various sources by efficient analytical support. Extraction, storage, and handling are described in detail. We also describe the effect of heat and time on amount of lycopene during extraction. Purification and applications are considered to understand lycopene's nutraceutical, epidemiological, and pharmaceutical importance, as well. ISSN: 10942912

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Title: Effects of supercritical fluid extraction parameters on lycopene yield and antioxidant activity

(超临界流体法萃取特性对番茄红素的产量和抗氧化剂活性的影响)

Author(s): Yi C (Yi, Chun)1,2, Shi J (Shi, John)1, Xue SJ (Xue, Sophia Jun)1, Jiang YM (Jiang, Yueming)2, Li D (Li, Dong)3 Times Cited: 1 Abstract: The effects of various parameters of supercritical carbon dioxide (SC-CO2,) fluid extractions of tomato skins on the extraction yields and antioxidant activities of lycopene-rich extracts were investigated. A Box-Behnken design was applied to study the effects of three independent variables (temperature ranging from 40 to 100 degrees C, pressure ranging from 20 to 40 MPa, and flow rate ranging from 1.0 to 2.0 mL/min) on lycopene yield. The model showed good agreement with the experimental results, by the coefficient of determination (r(2) = 0.9834). Temperature, pressure, and the quadratic term for the temperature of SC-CO2 extraction were large significantly positive factors affecting lycopene yield (P < 0.05). The maximum total lycopene content of 3 1.25 mu g/g of raw tomato was extracted at the highest temperature of 100 degrees C, 40 MPa and 1.5 mL/min. TEAC assay was applied to assess the antioxidant activity of lycopene-rich extracts from SC-CO2 fluid extraction. The effects Of SC-CO2 fluid extraction parameters on the antioxidant activities of the extracts differed with the yield. For each unit of lycopene extract, the antioxidant activity level was constant below 70 degrees C, but then gradually decreased above 70 degrees C due to isomerization

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