有机化学试题及答案--生物类(5套题)

1. 苯 酚 苯 胺 苄 醇2. 乙 醛Tollens 丙 酮 乙 醇3. 丁 烷Br2/CCl4 1-丁炔 1-丁烯4. 蔗 糖 D-果糖 D-葡萄糖红棕色褪去Br2H2O无沉淀Ag白色FeCl3H2O显色饱和NaHSO3白色 Ag(NH3)+灰白色 TollensBr2AgH2O红棕色褪去

七、 完成下列化合物的转化（所需试剂任选，每小题5分，共15分）

Br 1.CH3CH2 CH CH3CNKCNC2H5OH 2.CH3CH2CH3CHKOHC2H5OHCN CHH2OH+, T, P①C2H5MgBr/Et2O②H3O+NaNO2/HCl。0~5 CCH3 CH3H3OH CH2CH3CHCH3CH3CH3 C CH2CH3OHCH3N2+Cl-KMnO4H+KCNCuCNHOOC COOH CuCH3CCH3O+CH3CH CH CH3CH3HOOCCHOBr2CCl4CH3CHCOOH BrCH3CHBr CH CH33.CH3NH2CH3CNH3O+COOH

八、 推导结构（每小题5分，共15分）

O OH 1. A: (CH3)2CHCCH2CH3 B: (CH3)2CHCHCH2CH3OC: CH3CH2CHO D: CH3CCH3COOHCOOH2. A: B:C:OHOOCCH3O3. A:OB: HOOCCH2CHCOOC2H5OCH3D: H5C2OOCCH2CHCOOC2H5CH3COOHCOOHD: O2NOCH3OCH3: HOOCCHCH2COOC2H5CH3 C