有机化学-第五版-华北师范大学等-李景宁-全册-课后习题答案（完整版）

(1)CH3CHCH2COOH+ClCH3CH2CH2COCl+ClH2OCH3CHCH2COO+H3O无明显热效应H2OCH3CH2CH2COOH+HCl+C2H5OH(2)CH3CH2CH2COOC2H5+NH2OH.HClCH3CH2CH2COONHOHOFeCH3CH2CH2COONHOH+FeCl3CH3CH2CONH2+NH2OH.HClC3CH2CNHO+3HCl3无反应无反应CH3OCH2COONa+CO2CH3COONa+CH3CONHNa+2CH3COOH(3)CH3COOC2H5+NaHCO3NaHCO3NaOHNaOHH2OH2OCH3OCH2COOH+(4)CH3COONH4CH3CONH2++++NH3H2O(5)(CH3CO)2OCH3COOC2H5放热反应无反应

答案：

CH2+HBr

过氧化物CH2BrNaCNCH2CN 答案：

CH3COCH3MgTiCl3

OHOHCH3OCH3CCHCH3CC(CH3)3Br2,NaOH(CH3)3CCOOH+CHBr3

OHOH

答案：

(CH3)2CHBrMg乙醚

(CH3)2CHMgBr环氧乙烷(CH3)2CH2CH2OMgBrPBr3HCNaNH2(CH3)2CHCH2CH2BrCNa+CH3CH2CH2CH2BrHCCCH2CH2CH2CH3NaCCCH2CH2CH2CH3(CH3)2CHCH2CH2Br(CH3)3HCH2CH2CH2,Pd-BaSO4CCH2CH2CH2CH3HCCCH2CH2CH2CH3H

(CH3)3CHCH2CH2

答案：

HBrCH2CH(CH2)8COOH过氧化物

BrCH2(CH2)9COOHCH3COCH2COOEt2BuLi°-78 CLiCH2COCHLiCOOEt(1)BrCH2(CH2)9COOH(2)NaBH4H3O+EtOOCCH2COCH2CH2(CH2)9COOHEtOOCCH2CH(CH2)11COOHOH-H2OEtOOCCHCH(CH2)11COOHH2,NiEtOOC(CH2)11COOHEtOHHEtOOC(CH2)11COOEt

答案：

OCOOHCOOHCOOC2H5OHCHOONa25COOC2H5OHCOOC2H5C2H5OOHH+OOC2H5COOC2H5C2H5OONaCOOC2H5OC2H5COOHC2H5Br(1)OH-(2)H3O+O

C2H5

答案：

2CH2(COOC2H5)2C2H5ONa2NaCH2(COOC2H5)2CHC(COOC2H5)2CH2C(COOC2H5)2BrC2H5BrCH2CH(COOC2H5)22C2H5ONaBrC2H5BrCH2CH(COOC2H5)2OH5C2OCCOOC2H5COOH(1)OH-(2)H3O+,H5C2OCOCOOC2H5COOH

答案：

CH3COOHCH2OHKMnO4LiAlH4CH3CH2BrCOOHCH2CNCH2OHCH2COOC2H5PBr3NaCNC2H5OHHClCH2BrCH2CNCH2COOC2H5C2H5ONaO(1)OH-(2)H3O+O

COOC2H5

答案：

HOOHClSO3H

HOOHHO3SNO2HOHNO3OHH3O+SO3HNO2HOOHH2SO4

HO3SSO3H